You have a lot to learn but nothing too daunting if you are willing to cover some basics. You mention, you have some application without redundancy, are you planning to make them redundant when you virtualize them. Think about features you would like from virtualising your data center i.e. vmotion, ha, drs and so on. Also, think about growth, are you likely add some more servers. Approach this with end goal in mind, and work backwards.
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